Spectrophotometric determination of thorium with 2-(2-thiazolylazo)-5-dimethylaminophenol in the presence of cetylpyridinium chloride
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چکیده
منابع مشابه
Spectrophotometric Determination of Uranium Using 2-(2-Thiazolylazo)-p-Cresol (TAC) in the Presence of Surfactants
No presente trabalho apresenta-se um método seletivo e sensível para rápida determinação de urânio usando o 2-(2-Tiazolilazo)-p-Cresol (TAC). O TAC reage com o urânio(VI) em pH 6,5 formando um complexo estável por pelo menos 3 h. Brometo de N-cetil-N,N,N-trimetil amônio (CTAB) e triton X-100 foram usados para aumento da sensibilidade e solubilidade do sistema respectivamente. O método permite a...
متن کاملSimultaneous derivative spectrophotometric determination of zinc and cadmium with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol in the presence of cetylpyridinium chloride.
A selective and sensitive derivative photometric method has been developed for the determination of trace amounts of Zn2+ with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol in the presence of cetylpyridinium chloride, a cationic surfactant. The molar-absorption coefficient and analytical sensitivity of the 1:2 complex at 554 nm are 1.19 x 10(5) L mol(-1) cm(-1) and 0.56 ng mL(-1), respectively....
متن کاملSpectrophotometric determination of samarium(III) with chrome azurol S in the presence of cetylpyridinium chloride.
A sensitive, simple method for the determination of trace amounts of samarium by spectrophotometry is described based on the formation of the samarium-chrome azurol S (CAS) complex in micellar medium. The molar absorptivities of the complexes at pH 7.5 at 505 nm were 3.6x10(4) and 1.4x10(5) l mol(-1) cm(-1) for water media and cetylpyridinium chloride (CPC), respectively. Beer's law is obeyed f...
متن کاملSelective Cloud Point Extraction for the Spectrophotometric Determination of Cetylpyridinium Chloride in Pharmaceutical Formulations
In this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (CPC) in pharmaceutical products using cloud point extraction (CPE) technique. The method is based on cloud point extraction of the CPC in alkali conditions using of nonionic surfactant Triton X-114. Under selected conditions, the calibration ...
متن کاملSelective Cloud Point Extraction for the Spectrophotometric Determination of Cetylpyridinium Chloride in Pharmaceutical Formulations
In this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (CPC) in pharmaceutical products using cloud point extraction (CPE) technique. The method is based on cloud point extraction of the CPC in alkali conditions using of nonionic surfactant Triton X-114. Under selected conditions, the calibration ...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1979
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.28.12_754